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Identify an unknown substance through a series of tests that should systematically eliminate all other possible substances.  

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A2 - Assessed Practical (Skill P) Introduction. Alcohols. 'Alcohols are a family of organic compounds in which the -OH functional group is attached to a hydrocarbon chain', pg. 296 Chemistry for Advanced level, Third edition. A substance can be tested for the presence of this functional group by selective oxidation. 'A solution of acidified potassium dichromate ions is often used as the oxidising agent. In the reaction the orange dichromate (VI) ions are reduced to green chromium (III) ions' pg 308, Chemistry for Advanced Level, Third Edition, Cr2O72 - + 14H+ + 6e- 2Cr3+ + 7H2O The overall equation is: 2Cr2O72 -(aq) + 3C2H5OH(l) + 16H+(aq) 4Cr3+(aq) + 3CH3CO2H(aq) + 11H2O(l) Ketones. Oxidation of secondary alcohols produces ketones, e.g. propanone and contains a C=O bond, where the carbon atom is also bonded to a CH3 group. 'The basic method of identification of an unknown carbonyl compound is to make a solid derivative and then measuring the melting...

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