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Rates of reaction of halogenoalkanes.


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Rates of reaction of halogenoalkanes.

... Rates of reaction of halogenoalkanes. Aim; the aim of this experiment is to investigate the factors that affect the rate of nucleophilic substitution reaction. (ref1) Nucleophilic substitution is where an "electron rich" nucleophile selectively bonds with partially positive charge of an atom attached to a group or atoms called the leaving group; the positive or partially positive atom is referred to as an electrophile. Apparatus Goggles, for eye protection Test tube rack and Test tubes 250cm beaker Pipette Thermometer to measure the temperature Measuring cylinder Halogenoalkes 1. 1-Chlorobutane(C2H5Cl) 2. 1-Bromobutane(C2H5Br) 3. 1-Iodobutane(C2 H5 I) Stop Watch Diluted aqueous Sodium Hydroxide Silver Nitrate solution at 0.1 mol dm-3 Ethanol Prediction I predict that iodoalkane would react fastest because it's got the weakest bond because iodines the biggest molecule so the bond is longer and therefore weaker. The Electronegativity is factor that can have some influence in reaction of the haogenoalkane but in this case it is not as significant. In this reaction the general equation

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"I've rated this on the assumption that it is a planning exercise only. On the whole, this is a strong write-up. The chemistry underlying the investigation is clearly set out, and I am confident that the author has a good grasp of the theoretical principles involved. The consideration of variables to control in particular is well written and a crucial inclusion in the report that is too often missed. The author should give some consideration to the structure of the report (e.g. by considering the ordering of the topic headings and the content that fits below each heading), and the language should be tightened up as it feels a little too 'chatty' in places rather than being suitable for a scientific document. As a result I don't feel that I can give this a 5, but it's certainly a strong 4. TSR user: Illusionary"
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