Comparing the Enthalpy Changes of Combustion of Different Alcohols
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Comparing the Enthalpy Changes of Combustion of Different Alcohols By Steven Duong Background Information The enthalpy change of the combustion of a fuel depends on two things. First, there is the number of bonds to be broken and made - and that depends on the size of the molecule involved. The ?H?c also depends on the type of bonds involved: e.g. combustion of a) methane and b) methanol a) CH4 + 2O2 CO2 + 2H2O H O=O O=C=O H-O-H O=O H-O-H H C H H b) CH3OH + 11/2O2 CO2 + 2H2O H O=O O=C=O H-O-H O H-O-H H C O - H H From the examples shown above, the products are the same, but the key difference is that methanol already has an O-H bond; one of the bonds to oxygen is already made, unlike with methane, where all the new bonds have been made. The energy released during combustion comes from the making of...

