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Fractional DistillationBOILING POINTS AND STRUCTURES OF HYDROCARBONS The boiling points of organic compounds can give important clues to other physical properties  

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Fractional Distillation BOILING POINTS AND STRUCTURES OF HYDROCARBONS The boiling points of organic compounds can give important clues to other physical properties. A liquid boils when its vapour pressure is equal to the atmospheric pressure. Vapour pressure is determined by the kinetic energy of molecules. Kinetic energy is related to temperature and the mass and velocity of the molecules. When the temperature reaches the boiling point, the average kinetic energy of the liquid particles is sufficient to overcome the forces of attraction that hold molecules in the liquid state. Then these molecules break away from the liquid forming the gas state. Vapour pressure is caused by equilibrium between molecules in the gaseous state and molecules in the liquid state. When molecules in the liquid state have sufficient kinetic energy, they may escape from the surface and turn into a gas. Molecules with the most independence in individual motions achieve sufficient kinetic...

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